Sasuke vs. the Raikage!! (サスケVS雷影!!, Sasuke Bāsasu Raikage!!) is chapter 463 of the Naruto manga.
Because of A's Lightning Release Armour, Sasuke is unable to deal much damage to him. To put them on the same playing field, Sasuke uses an early stage of Susanoo, so that A is unable to deal a finishing blow. He then tries to use Amaterasu on A, but the Lightning Release Armour also gives A the speed to evade the flames. Sasuke then surrounds himself with Amaterasu in an attempt to stop A from attacking him. Despite this, A continues with his assault.