"Sasuke vs. the Raikage!!" (サスケVS雷影!!, Sasuke Bāsasu Raikage!!) is chapter 463 of the original Naruto manga.
Because of the Fourth Raikage's Lightning Release Chakra Mode, Sasuke is unable to deal much damage to him. To put them on the same playing field, Sasuke uses an early stage of Susanoo, so that the Raikage is unable to deal a finishing blow. He then tries to use Amaterasu on the Raikage, but the Lightning Release Chakra Mode also gives the Raikage the speed to evade the flames. Sasuke then surrounds himself with Amaterasu in an attempt to stop the Raikage from attacking him. Despite this, the Raikage continues with his assault.