"Kakashi vs. Pain!!" (カカシVSペイン!!, Kakashi Bāsasu Pein!!) is chapter 422 of the original Naruto manga.
Pain's search for Naruto continues, but none of Konoha's ninja are willing to tell him anything. Tsunade summons Katsuyu, who she instructs to seek out and adhere to every Konoha citizen so that she can monitor and heal them all remotely. Kakashi's fight with the Deva and Asura Path continues, but he cannot overcome their shared Rinnegan vision. The Asura Path modifies its body for battle and attacks him, but he is saved by a team led by Chōza Akimichi.