Scorpion's puppeteer can shoot fire from the pipes in its hands, making them like flame-throwers. The flames are fierce enough to melt rocks and incinerate a metal kunai that was thrown at it near instantly. The ammunition is sealed in the the first scroll on its back.[1]. During Kankurō's use of the puppet, the ammunition scroll is nowhere to be seen, implying that the flame-throwers may be used without it.
Trivia
Shura's umbrella also has a flame-thrower installed within it.
In the Chikara Arc, a reincarnated Iwa-nin uses a flamethrower device in battle.